University of Michigan researchers have developed a laser-based method that could be used to detect chemicals such as explosives and dangerous gases quickly and accurately.
Eventually, this method could be used in systems placed in airports, for the environmental monitoring of pollutants or even in battlefields, said author Steven Cundiff, physics professor in the College of Literature, Science, and the Arts. The study, conducted by physics research fellow Bachana Lomsadze, publishes today in Science.
Lomsadze and Cundiff’s method combines two techniques that speed up laser-based detection of chemicals while doing so accurately. The first technique is based on the same idea as nuclear magnetic resonance spectroscopy, which uses radio frequencies to identify the structure of molecules. Here, the researchers use a method called multi-dimensional coherent spectroscopy, or MDCS. MDCS uses ultrashort laser pulses to read types of gases like a bar code. When the scientists bounce the laser pulses through the mixture of gases, those pulses can “read” the specific wavelengths of light—or color—that specific gases absorb.
“If you have light going through the gas, and, for example, you use a prism to separate white light into colored light, in the rainbow spectrum you’d see there’d be black stripes,” Cundiff said. “Where the black stripes are almost gives you a barcode that tells you what kind of molecule is in the sample.”
Scientists have been working on similar, simpler methods. Many important molecules have a very rich spectra for certain colors of light—although the “colors” may actually be in the infrared, so not visible the human eye—which makes them easily identifiable. But this becomes difficult when scientists try to identify gases in a mixture. Previously, scientists relied on comparing what they measured against a catalogue of molecules, a process that requires high performance computers and a significant amount of time.
“It’s like trying to look at three people’s fingerprints on top of each other. This is a stumbling block for using these methods in a real-world situation,” Cundiff said. “Our method takes about 15 minutes to a few hours using traditional approaches to MDCS.”
To speed up the process while preserving its accuracy, the U-M researchers combined MDCS with another method called dual comb spectroscopy.